繊維学部研究紹介_2020_英語版
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サイズW7.5cm×H4.35cm配置位置横11cm、縦2.5cmNNOPh2PCatalystRROHOHCatalystC6H5COCl, i -Pr2EtNRROCOC6H5OHUp to 94 % ee18214151617He678910CNOFNe1415161718SiPSClAr33343536AsSeBrKrDeveloping novel organocatalysts for highly stereoselective synthesis of organic moleculesParticleSolidApplying colloid and interface chemistry to nano‐technological and biological systems42Department of Chemistry and MaterialsDepartment of Chemistry and MaterialsOutlookforresearchOutlookforresearchOutlook for students after graduationOutlook for students after graduationOrganicmoleculessometimescomeinachiralformwithanenantiotopicrelationship.Iamcarryingoutresearchfocusedprimarilyonthedevelopmentofanasymmetricalcatalysttoselectivelysynthesizeonesideofachiralmolecule.Mygoalindoingsoistocreatenewcatalyststhatarehighlyselectiveandhighlyactivated,thatdonotuseraremetals,andthatcanbesynthesizedsimply.Expectedapplicationsincludethefunctionalizationofglycerin,atypeofbiomass,usingtheasymmetricesterificationreactionandtheeasysupplyofopticallyactivealcoholandamine,inadditiontothecarbon‐carbonbond‐formingreactionthatisimportantfororganicsynthesis.Graduates have gone to work for manufactures of low‐and high‐polymer products and pharmaceuticals.AssociateProfessorTetsuyaFujimotoAssociateProfessorFujimotofirstcompletedaShinshuUniversityGraduateSchoolofEngineeringresearchcoursespecializinginthestudyoffunctionalpolymers.Hisareaofresearchisorganicsyntheticchemistry,andhisworkfocusesonnewmethodsfororganicsynthesisandthedevelopmentofnewcatalysts.Aviewofthelab.Numerousreagents,solvents,andglasscontainersareusedtosynthesizethetargetorganiccompounds,yieldingsubstanceswhosestructurecanbeconfirmedusingNMR.Anasymmetricesterificationsolutiondesignedbasedonatomicprinciples,andassociatedreactions.Esterificationproceedsbydifferentiatingbetweenthetwosymmetricalhydroxylsinthediol.In my laboratory, we use colloid and interfacial science to study nano‐technological and biological systems.Nano‐technologicalapplications:Weareusinginterfacialforcestoproduceamonolayerofnanoparticlesatanair‐waterinterfacewithacontrolledpacking.Suchamonolayercanbeusedtoproducemagneticorsemiconductormaterials.Ourgoalistodeterminehowtocreatehigh‐qualitydevicesatlowcostbydetermining(1)theeffectsoftheparticlematerial,size,andshapeonthephysicalpropertiesofthemonolayerand(2)theforcesandfactorscontrollingthestructuringandinteractionsoftheparticlesattheinterface.Biologicalapplications:Weareresearching(1)thephysicalpropertiesofpolysaccharidesinordertoproducematerialsthatcanactaslubricantfilmsinjointsand(2)howtocontroltheinteractionsoflipidsincellmembraneswithothermoleculessoastoinhibittheiraggregation,whichcancausehealthproblemssuchasmetabolicsyndrome.Iamstudyingnano‐technologicalandbiologicalsystemsbyusingcolloidandinterfacialphysicalchemicaltechniques.Myfocusisondeterminingthefundamentalpropertiesofthesesystemsandhowtheycanbecontrolled.Inoursociety,peoplehavetothinkandmakedecisionsonnewandunknowntopicseveryday.Inmylab,wearelearninghowtothinkandmakedecisionsthoughourresearchonnewandunknownscience.Associate ProfessorCathy McNameeEducation:B.Sc. (hons), B.A.: University of Queensland, AustraliaD.Sc.: Kyoto University, Japan International collaborations:Max Planck Institute for Polymer Science, GermanyResearch Field:Colloid and Interface ScienceA particulate monolayer that has been transferred to a solid substrateTheinteractionofglucoseorinsulinwithamodelbiologicalmembraneisdeterminedbyusingaLangmuirtroughandfluorescenceimagingtechniques.

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