Flurofullerene

フッ化フラーレンギャラリー

C60	分子の対称性	Ih
	結晶構造	FCC (Fm-3m) 1.4154 nm (270 K) SC (Pa-3) 1.40708 nm (170 K)
	物性	体積弾性率: 15.6 GPa[1]、体膨張率: 0.57*10^-4 K^-1
	電子構造	For Vapor Phase LUMO: -2.65eV, HOMO: -7.6eV For Solid Phase LUMO: -3.6eV, E_F: -4.3eV, HOMO: -6.2eV, C1s: -289.0eV
C60F2	分子の対称性	C2_v[2]
C60F16		[3]
C60F18	分子の対称性	C3_v[4]
	結晶構造	For C₆₀F₁₈(C₇H₈)[5] Monoclinic P2₁/n a=1.1532, b=2.1501, c=1.6261 nm, β=101.798, Z=4
	物性
C60F20		[6]
C60F36	分子の対称性	T, Th[7]
	結晶構造	BCC a=13.02[8]
	物性	体積弾性率: 14.3 GPa[9]、体膨張率: 0.70*10^-4 K^-1[10]
	電子構造	LUMO: -5.2eV, HOMO: -8.2eV
C60F48	分子の対称性	D3, S6[11]
	結晶構造	For C₆₀F₄₈[8][12] BCT a=11.852, c=17.91, Z=2 FCC a=17.373 (358 K) For For C₆₀F₄₈2C₆H₃Me₃[13] Cubic Pa-3 a=23.229, Z=8
	物性
	電子構造	LUMO: -5.0eV, E_F: -5.4eV, HOMO: -8.4eV

[1] H. Horikawa, T. Kinoshita, K. Suito, A. Onodera, Compressiblity measurement of C60 using synchrotron radiation Solid State Commun., 114, 121, 2000
[2] O. V. Boltalina, A. Y. Lukonin, J. M. Street, R. Taylor, C60F2 exists!, Chem. Comm. 1601-1062, 2000
[3] A. G. Avent, O. V. Boltalina, A. Y. Lukonin, J. M. Street, R. Taylor, Isolation and characterization of C60F16; a key to understanding fullerene addition patterns, Perkin Trans. 2, 1359, 2000
[4] O. V. Boltalina, V. Y. Markov, R. Taylor, M. P. Waugh Preparation and characterisation of C60F18 Chem. Comm., 2549-2550, 1996
[5] I. S. Neretin, K. A. Lyssenko, M. Y. Antipin, Y. L. Slovokhotov, O. V. Boltalina, P. A. Troshin, A. Y. Lukonin, L. N. Sidrov, R. Taylor Angew. Chem. Int. Ed., 39, 3273-3276, 2000
[6] O. V. Boltalina, V. Y. Markov, P. A. Troshin, A. D. Darwish, J. M. Street, R. Taylor, C60F20:"Saturnene", an extraordinary squashed fullerene, Angew. Chem. Int. Ed., 40, 787-789, 2001
[7] O. V. Boltalina, A. Y. Borschevskii, L. N. Sidorov, J. M. Street, R. Taylor Preparation of C60F36 and C70F36/38/40 Chem. Commun., 529-530, 1996
[8] S. Kawasaki, T. Aketa, F. Okino, H. Touhara, O.V. Boltalina, I.V. Gol'dt, S.I. Troyanov and R. Taylor, Crystal structures of fluorinated fullerenes C60F36 and C60F48, J. Phys. Chem. B, 103, 1223-1225, 1999
[9] S Kawasaki, unpublished work
[10] S Kawasaki, unpublished work
[11] A. A. Gakh, A. A. Tuinman, J. L. Adcock Selective synthesis and structure determination of C60F48 J. Am. Chem. Soc., 116, 819-820, 1994
[12] S. Kawasaki, F. Okino and H. Touhara, Crystal structures and phase transformations of the fluorinated fullerenes, Mol. Crsyt. and Liq. Cryst., 340, 629-633, 2000
[13] S. I. Troyanov, P. A. Troshin, O. V. Boltalina, I. N. Ioffe, L.N. Sidrov, E. Kemnitz Two isomers of C60F48: An indented fullerene Angew. Chem. Int. Ed., 40, 2285, 2001